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CO2 capture Main articles: Carbon dioxide scrubber and carbon dioxide air capture Capturing CO2 might be applied to large point sources, such as large fossil fuel or biomass energy facilities, industries with major CO2 emissions, natural gas processing, synthetic fuel plants and fossil fuel-based hydrogen production plants. Air capture is also possible. But air away from the point source also contains oxygen, and so capturing air, scrubbing the CO2 from the air, and then storing the CO2 could slow down the oxygen cycle in the biosphere. Concentrated CO2 from the combustion of coal in oxygen is relatively pure, and could be directly processed. In other instances, especially with air capture, a scrubbing process would be needed. Broadly, three different types of technologies exist: post-combustion, pre-combustion, and oxyfuel combustion. In ost combustion capture, the CO2 is removed after combustion of the fossil fuel - this is the scheme that would be applied to fossil-fuel burning power plants. Here, carbon dioxide is captured from flue gases at power stations or other large point sources. The technology is well understood and is currently used in other industrial applications, although not at the same scale as might be required in a commercial scale power station. The technology for pre-combustion is widely applied in fertilizer, chemical, gaseous fuel (H2, CH4), and power production. In these cases, the fossil fuel is partially oxidized, for instance in a gasifier. The resulting syngas (CO and H2) is shifted into CO2 and more H2. The resulting CO2 can be captured from a relatively pure exhaust stream. The H2 can now be used as fuel; the carbon dioxide is removed before combustion takes place. There are several advantages and disadvantages when compared to conventional post combustion carbon dioxide capture. In oxy-fuel combustion the fuel is burned in oxygen instead of air. To limit the resulting flame temperatures to levels common during conventional combustion, cooled flue gas is recirculated and injected into the combustion chamber. The flue gas consists of mainly carbon dioxide and water vapor, the latter of which is condensed through cooling. The result is an almost pure carbon dioxide stream that can be transported to the sequestration site and stored. Power plant processes based on oxyfuel combustion are sometimes referred to as "zero emission" cycles, because the CO2 stored is not a fraction removed from the flue gas stream (as in the cases of pre- and post-combustion capture) but the flue gas stream itself. It should be noted, however, that a certain fraction of the CO2 generated during combustion will inevitably end up in the condensed water. To warrant the label "zero emission" the water would thus have to be treated or disposed of appropriately. The technique is promising, but the initial air separation step demands a lot of energy. Plants that produce ethanol by fermentation generate cool, essentially pure CO2 that can be pumped underground. Fermentation produces slightly less CO2 than ethanol by weight. World ethanol production in 2008 is expected to be about 16 billion gallons or 48 million tonnes. An alternate method, which is under development, is chemical looping combustion (CLC). Chemical looping uses a metal oxide as a solid oxygen carrier. Imperial Oakland Athletics Cue Stick Metal oxide particles react with a solid, liquid or gaseous fuel in a fluidized bed combustor, producing solid metal particles and a mixture of carbon dioxide and water vapor. The water vapor is condensed, leaving pure carbon dioxide which can be sequestered. The solid metal particles are circulated to another fluidized bed where they react with air, producing heat and regenerating metal oxide particles that are recirculated to the fluidized bed combustor. A variant of chemical looping is calcium looping, which uses the alternate carbonation and then calcination of a CaO based carrier as a means of capturing CO2. A few engineering proposals have been made for the more difficult task of capturing CO2 directly from the air, but work in this area is still in its infancy. Global Research Technologies demonstrated a pre-prototype in 2007. Capture costs are estimated to be higher than from point sources, but may be feasible for dealing with emissions from diffuse sources like automobiles and aircraft. The theoretically required energy for air capture is only slightly more than for capture from point sources. The additional costs come from the devices that use the natural air flow. Removing CO2 from the atmosphere is a form of geoengineering by greenhouse gas remediation. Techniques of this type have received widespread media coverage as they offer the promise of a comprehensive solution to global warming if they can be coupled with effective carbon sequestration technologies. It is more usual to see such techniques proposed for air capture, than for flue gas treatment. Carbon dioxide capture and storage is more commonly proposed on plants burning coal in oxygen extracted from the air, which means the CO2 is highly concentrated and no scrubbing process is necessary. According to the Wallula Energy Resource Center in Washington state, by gasifying the coal, it is possible to capture approximately 65% of carbon dioxide embedded in coal and sequester them into the solid form. Through Cement Captures the CO2 from industrial smokestacks to be stored in cement during production. Five percent of the CO2 emissions are produced by manufacturing cement globally. Process of turning carbon into cement: Seawater is the main resource for this process. Extract the NaCl from the other minerals to make salt water. Electrolyze and split the water and salt to make sodium hydroxide (lye) and hydrochloric acid. Neutralize the acid in a reaction with silicate rocks, producing sand and magnesium chloride, which can be used together or separately to melt ice on roads. Combining the highly alkaline sodium hydroxide solution with carbon dioxide streaming from a smokestack, trapping the carbon dioxide in the form of baking soda (sodium bicarbonate). Add the baking soda to seawater, which contains magnesium and calcium. The soda triggers a series of reactions, precipitating a magnesium and calcium carbonate that can be used as cement. Some of the regulations made to greenhouse-gas emissions, such as carbon tax could eventually make this process profitable as well as environment friendly. CO2 transport After capture, the CO2 would have to be transported to suitable storage sites. This is done by pipeline, which is generally the cheapest form of transport. In 2008, there were approximately 5,800 km of CO2 pipelines in the United States, used to transport CO2 to oil production fields where the CO2 is injected in older fields to extract oil. The injection of CO2 to produce oil is generally called "Enhanced Oil Recovery" or EOR. In addition, there are several pilot programs in various stages to test the long-term storage of CO2 in non-oil producing geologic formations. These are discussed below. COA conveyor belt system or ships could also be used. These methods are currently used for transporting CO2 for other applications. According to the Congressional Research Service, "There are important unanswered questions about pipeline network requirements, economic regulation, utility cost recovery, regulatory classification of CO2 itself, and pipeline safety. Furthermore, because CO2 pipelines for enhanced oil recovery are already in use today, policy decisions affecting CO2 pipelines take on an urgency that is unrecognized by many. Federal classification of CO2 as both a commodity (by the Bureau of Land Management) and as a pollutant (by the Environmental Protection Agency) could potentially create an immediate conflict which may need to be addressed not only for the sake of future CCS implementation, but also to ensure consistency of future CCS with CO2 pipeline operations today. CO2 storage (sequestration) It has been suggested that this section be split into a new article. (Discuss) Main article: CO2 sequestration Various forms have been conceived for permanent storage of CO2. These forms include gaseous storage in various deep geological formations (including saline formations and exhausted gas fields), liquid storage in the ocean, and solid storage by reaction of CO2 with metal oxides to produce stable carbonates. Geological storage Also known as geo-sequestration, this method involves injecting carbon dioxide, generally in supercritical form, directly into underground geological formations. Oil fields, gas fields, saline formations, unminable coal seams, and saline-filled basalt formations have been suggested as storage sites. Various physical (e.g., highly impermeable caprock) and geochemical trapping mechanisms would prevent the CO2 from escaping to the surface. CO2 is sometimes injected into declining oil fields to increase oil recovery. Approximately 30 to 50 million metric tonnes of CO2 are injected annually in the United States into declining oil fields.. This option is attractive because the geology of hydrocarbon reservoirs are generally well understood and storage costs may be partly offset by the sale of additional oil that is recovered. Disadvantages of old oil fields are their geographic distribution and their limited capacity, as well as that the subsequent burning of the additional oil so recovered will offset much or all of the reduction in CO2 emissions. Unminable coal seams can be used to store CO2 because CO2 adsorbs to the surface of coal. However, the technical feasibility depends on the permeability of the coal bed. In the process of absorption the coal releases previously absorbed methane, and the methane can be recovered (enhanced coal bed methane recovery). The sale of the methane can be used to offset a portion of the cost of the CO2 storage. However, burning the resultant methane would produce CO2, which would negate some of the benefit of

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